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in a two-phase mixture of liquid and vapor To the left of the critical point C a reduction in pressure along a line such as B D is accompanied by vaporization of liquid from bubblepoint to dewpoint, as would be expected However, if the original condition corresponds to point F , a state of saturated vapor, liquefaction occurs upon reduction of the pressure and reaches a maximum at point G, after which vaporization takes place until the dewpoint is reached at point H This phenomenon is called retrograde condensation It can be important in the operation of deep natural-gas wells where the pressure and temperature in the underground formation are at conditions represented by point F If the pressure at the wellhead is that of point G, considerable liquefaction of the product stream is accomplished along with partial separation of the heavier species of the mixture Within the underground formation itself, the pressure tends to drop as the gas supply is depleted If not prevented, this leads to the formation of a liquid phase and a consequent reduction in the production of the well Repressuring is therefore a common practice; ie, lean gas (gas from which the heavier species have been removed) is returned to the underground reservoir to maintain an elevated pressure A P-T diagram for the ethane(l)/n-heptane(2) system is shown in Fig 105, and a yl-xl diagram for several pressures for the same system appears in Fig 106 According to convention, one plots as yl and xl the mole fractions of the more volatile species in the mixture The maximum and minimum concentrations of the more volatile species obtainable by distillation at a given pressure are indicated by the points of intersection of the appropriate y -XI curve with the diagonal, for at these points the vapor and liquid have the same composition They are in fact mixture critical points, unless yl = xl = 0 or yl = xl = 1 Point A in Fig 106 represents the composition of the vapor and liquid phases at the maximum pressure at which the phases can coexist in the ethaneln-heptane system The composition is about 77 mol-% ethane and the pressure is about 871 bar The corresponding point on Fig 105 is labeled M A complete set of consistent phase diagrams for this system has been prepared by ~arr-David'.

here may come a time when you d like your NXT robot to be able to communicate and share information with other NXT robots. Or, if you have a second NXT kit, you could build a remote control for your robot and give it commands using the second NXT Brick. To make all this happen requires a couple of blocks that will both be covered in this chapter. Many people find these blocks difficult or confusing, but they re really very simple if you understand the basic concept behind sending and receiving messages. Of course, sending and receiving message requires that both NXT blocks be connected via a Bluetooth connection. Connecting two or more NXT Bricks via Bluetooth is not covered here, so if you need help with this task, check the built-in Help file with your NXT software; you can find instructions for connecting two or more NXT devices using Bluetooth by reading either the SEND MESSAGE or RECEIVE MESSAGE block s documentation.

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'F H Ban-David, AIChE J, vol 2, p 426, 1956

Line 8 Line 10 The static method specified in Line 7 allows various options, like address, netmask, gateway, etc The address option here defines the interface IP address (192168145), the netmask option defines the subnet mask (2552552550), and the gateway option defines the default gateway (19216811) Line 11 The iface directive is being used to define a virtual interface named eth0:0 that will be configured using DHCP Line 15 The iface directive defines the physical name of the interface being processed In this case, it is the eth1 interface The iface directive in this example supports the inet option, which is using the dhcp option This means that the interface will be dynamically configured using DHCP Line 16 Line 18 These lines assign a static IPv6 address to the eth1 interface The address assigned in this example is 2001:DB8::3 with the netmask 64 After making and saving any changes to the interfaces file, the network interface can be brought up or down using the ifup command For example, after creating a new entry for the eth1 device, you would type

With heat capacities given by Eq (44), the expression for K2 becomes:

The sample interfaces file discussed here is a simple configuration The /etc/ network/interfaces file supports a vast array of configuration options that we barely scratched here Fortunately, the man page (man 5 interfaces) for the file is well documented

Values of AGO for many formation reactions are tabulated in standard reference^^ The reported values of AG-e not measured experimentally, but are calculated by Eq (1316) The determination of AS; may be based on the third law of thermodynamics, discussed in Sec 510 Combination of values from Eq (540) for the absolute entropies of the species taking part in the reaction gives the value of AS: Entropies (and heat capacities) are also commonly determined from statistical calculations based on spectroscopic data5 Values of AGOfZg8 a limited number of chemical compounds are listed in Table C4 of for App C These are for a temperature of 29815 K (25"C), as are the values of A H;298listed in the same table Values of AGO for other reactions are calculated from formation-reaction values in exactly the same way that A H O values for other reactions are determined from formationreaction values (Sec 44) In more extensive compilations of data, values of AGY and AH; are given for a wide range of temperatures, rather than just at 29815 K (25 C) Where data

The typical route command is structured as follows:

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